Mixed carboxylic/sulfonic anhydrides in peroxygen bleaching

ABSTRACT

A process of removing soil and/or stains from fabrics by immersing the fabrics in a peroxygen bleach bath containing as a peroxygen activator, an anhydride of a carboxylic acid with a sulfonic acid selected from the formulae consisting of 
     
         R.sub.1 --(SO.sub.2 OC(O)--R.sub.2).sub.n and (R.sub.1 --SO.sub.2 
    
      OC(O)) n  R 2   
     wherein n is an integer of 1 to 3; each of R 1  and R 2 , which may be alike or different, is selected from the class consisting of a 1 to 3 valent hydrocarbon radical derived from an alkane of 1 to 16 carbon atoms, a cycloalkane of 3 to 7 carbon atoms and an arene of 6 to 12 aromatic carbon atoms while taken together R 1  and R 2  can complete an o-phenylene or an o-naphthalene ring, said hydrocarbon radicals optionally bearing 1 to 3 substituents selected from the class consisting of alkoxy of 1 to 16 carbon atoms on the arene, aliphatic carboxamido of 1 to 16 carbon atoms on the arene, alkyl of 1 to 16 carbon atoms on the arene, benzamido on the arene, nitro, chlorine, bromine and fluorine. Also described are dry blend compositions containing the activator and peroxygen.

This invention relates to active oxygen compositions. In particular, theinvention is concerned with activated peroxygen compounds and theirapplication to laundering operations.

The use of bleaching agents as laundering aids is well known. In fact,such entities are considered necessary adjuncts for cleaning today'sfabrics which embrace a wide spectrum of synthetic, natural and modifiednatural fiber systems, each differing in washing characteristics.

Laundry bleaches generally fall into one of two categories; activeoxygen-releasing or peroxygen and active chlorine-releasing. Of the two,chlorine bleach is more likely to react with the various components of adetergent washing formulation than peroxygen bleaches. Moreover, fabricstreated with chlorine bleaches exhibit significant loss of strength anddepending on the frequency of bleaching, the useful life of the clothmay be appreciably reduced; with dyed fabrics, colors are oftendegraded. Another objection to chlorine bleaches is their pronouncedtendency to cause yellowing, particularly with synthetics and resintreated fabrics. Peroxygen bleaches are substantially free of suchadverse side effects.

Despite their many advantages, bleaching agents of the activeoxygen-releasing type are as a class not optimally effective until usetemperatures exceed about 85° C, usually 90° C, or higher. This rathercritical temperature-dependency of peroxygen bleaching agents andespecially the persalt bleaches such as sodium perborate poses a ratherserious drawback since many household washing machines are now beingoperated at water temperatures less than about 60° C, well below thosenecessary to render bleaching agents such as the perborates adequatelyeffective. Although the near boiling washing temperatures employed inEurope and some other countries favor the use of peroxygen bleaches, itcan be expected that such temperatures will be lowered in the interestof conserving energy. Consequently, where a comparatively high order ofbleaching activity at reduced temperature is desired, resort must be hadto chlorine bleaches despite their attendant disadvantages, i.e.,impairment of fabric strength, fabric discoloration, etc.

In an effort to realize the full potential of peroxygen bleaches, suchmaterials have been the focus of considerable research and developmenteffort over the years. One result of these investigations was thefinding that certain substances, activators as they are usually called,have the capacity of amplifying the bleaching power of peroxygencompounds below about 60° C where many home washing machines arecommonly operated, or preferably operated. Although the precisemechanism of peroxygen bleach activation is not known, it is believedthat activator-peroxygen interaction leads to the formation of anintermediate species which constitutes the active bleaching entity. In asense, then, the activator-peroxygen component functions as a precursorsystem by which the in situ generation of species providing effectivebleaching means is made possible.

Although numerous compounds have been proposed and tested as peroxygenbleach activators, a satisfactory candidate has thus far not beenforthcoming. Perhaps the primary objection is the failure to provide thedesired degree of bleaching activity within the limitations imposed byeconomically feasible practice. Thus, it is often necessary to utilizethe activator compound in inordinately high concentrations in order toachieve satisfactory results; in other instances, it is found that agiven activator is not generally applicable and thus may be usedadvantageously only in conjunction with rather specific and delimitedtypes of peroxygen bleaching agents. Other disadvantages characterizingmany of the activator compounds thus far contemplated include, forexample, the difficulties associated with their incorporation intodetergent powder compositions including stability problems and shortshelf life. Since many of the activators are liquids under normalconditions, the blending of such materials into solid products is notpractical, at least so far as home application is concerned. Moreover,ancillary techniques specifically devised for purposes of facilitatingactivator-detergent powder blending in such instances are ofteneconomically prohibitive, the results obtained failing to justify theinvolved costs.

Classes of compounds which are representative of prior art activatorsfor peroxygen bleaches include carboxylic acid anhydrides disclosed inU.S. Pat. Nos. 2,284,477, 3,532,634 and 3,298,775; carboxylic estersdisclosed in U.S. Pat. No. 2,955,905; N-substituted,N-acylnitrobenzenesulfonamides disclosed in U.S. Pat. No. 3,321,497;N-benzoylsaccharin disclosed in U.S. Pat. No. 3,886,078; N-acylcompounds such as those described in U.S. Pat. Nos. 3,912,648 and3,919,102 and aromatic sulfonyl chlorides disclosed in Japanese PatentPublication No. 90980 of Nov. 27, 1973.

While certain of these activators are effective in varying degrees,there is a continuing need for candidate compounds of improvedperformance and properties.

It has now been discovered that the bleaching capacity of peroxygenbleaches is increased by contacting them with an anhydride of acarboxylic acid with a sulfonic acid selected from the formulaeconsisting of

    R.sub.1 --(SO.sub.2 OC(O)--R.sub.2).sub.n and (R.sub.1 --SO.sub.2 OC(O)).sub.n --R.sub.2

wherein n is an integer of 1 to 3; each of R₁ and R₂, which may be alikeor different, is selected from the class consisting of a 1 to 3 valenthydrocarbon radical derived from an alkane of 1 to 16 carbon atoms, acycloalkane of 3 to 7 carbon atoms and an arene of 6 to 12 aromaticcarbon atoms, while taken together R₁ and R₂ can complete an o-phenyleneor an o-naphthalene ring, said hydrocarbon radicals optionally bearing 1to 3 substituents selected from the class consisting of alkoxy of 1 to16 carbon atoms on the arene, aliphatic carboxamido of 1 to 16 carbonatoms on the arene, alkyl of 1 to 16 carbon atoms on the arene,benzamido on the arene, nitro, chlorine, bromine and fluorine.

Another proviso attached to the characterization of the hereinactivators is that they exhibit sufficient solubility in the bleachingsystem in order to provide the requisite degree of activation for theactive oxygen-releasing bleaching agent. For instance, filling up thefree positions in R with bulky substituents could give rise to aderivative of low solubility. The particular type of substituent mayalso be a factor affecting the solubility factor.

Exemplary of carboxylic-sulfonic anhydride activators falling within theambit of the general formula and suitable for practicing the inventionare: ##STR1##

The carboxylic-sulfonic anhydrides belong to a known chemical class, thedescription of which is set forth in the technical literature. Forexample, there is disclosed in J.A.C.S., 85, 2446 (1963) the detailedpreparation and characterization of various anhydrides of the typeaforesaid from silver salts of sulfonic acids and carboxylic acidchlorides.

Using preparative techniques patterned after those of the J.A.C.S.publication, the carboxylic-sulfonic anhydrides of the invention aresynthesized in accordance with the following scheme: ##STR2## whereinR₁, R₂ and n have the previously assigned values and one of thereactants in each equation is always monofunctional with respect to theacid chloride or silver salt.

In carrying out the reactions aforesaid, approximately molar amountsbased on the functions of the silver salt and acid chloride are reactedin acetonitrile or other suitable organic solvent. The temperature ismaintained at about 20° C, using cooling means where necessary. Afterthe reaction is complete, the solvent is removed, preferably by vacuumdistillation and the crude solid extracted with ether or other suitableextractant from the insoluble silver chloride. The extracts arecombined, chilled and the resulting crystals recovered in the knownmanner such as filtration or centrifugation.

The carboxylic-sulfonic anhydrides are generally white crystallinesolids, soluble in the common organic solvents and exhibiting sharpmelting points.

In accordance with the invention, low temperature bleaching (i.e. belowabout 60° C) of stained and/or soiled fabrics is effected by contactingthem with a solution containing a carboxylic-sulfonic anhydrideactivator herein and an active oxygen-releasing compound. The activeoxygen-releasing compounds include such peroxygen compounds as hydrogenperoxide or those peroxygen compounds that liberate hydrogen peroxide inaqueous media. Examples of such peroxygen compounds are urea peroxide,alkali metal perborates, percarbonates, perphosphates, persulfates,monopersulfates and the like. Combinations of two or more peroxygenbleaches can be used where desired. The same holds true in the case ofthe activators. Although any number of peroxygen compounds are suitablein carrying out the invention, a preferred compound is sodium perboratetetrahydrate, since it is a readily available commercial product.Another suitable persalt is sodium carbonate peroxide.

Sufficient peroxygen compounds to provide from about 2 ppm to 2,000 ppmactive oxygen in solution are used. For home bleaching applications, theconcentration of active oxygen in the wash water is desirably from about5 to 100 ppm, preferably about 15 to 60 ppm. Sodium perboratetetrahydrate, the preferred peroxygen compound, contains 10.4% activeoxygen. The actual concentration employed in a given bleaching solutioncan be varied widely, depending on the intended use of the solution.

The concentration of the carboxylic-sulfonic anhydrides in the bleachingsolution depends to a large extent on the concentration of the peroxygencompound which, in turn, depends on the particular use for which a givencomposition is formulated. Higher or lower levels can be selectedaccording to the needs of the formulator. Overall, increased bleachingresults are realized when the active oxygen of the peroxygen compoundand carboxylic-sulfonic anhydride are present in a mole ratio in therange of from about 20:1 to 1:3, preferably from about 10:1 to 1:1.

Activation of the peroxygen bleaches is generally carried out in aqueoussolution at a pH of from about 6 to about 12, most preferably 8.0 to10.5. Since an aqueous solution of persalts or peracids is generallyacidic, it is necessary to maintain the requisite pH conditions by meansof buffering agents. Buffering agents suitable for use herein includeany non-interfering compound which can alter and/or maintain thesolution pH within the desired range, and the selection of such bufferscan be made by referring to a standard text.

For instance, phosphates, carbonates, or bicarbonates, which bufferwithin the pH range of 6 to 12 are useful. Examples of suitablebuffering agents include sodium bicarbonate, sodium carbonate, sodiumsilicate, disodium hydrogen phosphate, sodium dihydrogen phosphate. Thebleach solution may also contain a detergent agent where bleaching andlaundering of the fabric is carried out simultaneously. The strength ofthe detergent agent is commonly about 0.05% to 0.80% (wt.) in the washwater.

Although the activator, buffer and peroxygen compound can be employedindividually in formulating the bleach solutions of the invention, it isgenerally more convenient to prepare a dry blend of these components andthe resulting composition added to water to produce the bleach solution.A soap or organic detergent can be incorporated into the composition togive a solution having both washing and bleaching properties. Organicdetergents suitable for use in accordance with the present inventionencompass a relatively wide range of materials and may be of theanionic, non-ionic, cationic or amphoteric types.

The anionic surface active agents include those surface active ordetergent compounds which contain an organic hydrophobic group and ananionic solubilizing group. Typical examples of anionic solubilizinggroups are sulfonate, sulfate, carboxylate, phosphonate and phosphate.Examples of suitable anionic detergents which fall within the scope ofthe invention include the soaps, such as the water-soluble salts ofhigher fatty acids or rosin acids, such as may be derived from fats,oils, and waxes of animal, vegetable or marine origin, e.g., the sodiumsoaps of tallow, grease, coconut oil, tall oil and mixtures thereof; andmixtures thereof; and the sulfated and sulfonated synthetic detergents,particularly those having about 8 to 26, and preferably about 12 to 22,carbon atoms to the molecule.

As examples of suitable synthetic anionic detergents the higher alkylmononuclear aromatic sulfonates are preferred particularly the LAS typesuch as the higher alkyl benzene sulfonates containing from 10 to 16carbon atoms in the alkyl group, e.g., the sodium salts such as decyl,undecyl, dodecyl (lauryl), tridecyl, tetradecyl, pentadecyl, orhexadecyl benzene sulfonate and the higher alkyl toluene, xylene andphenol sulfonates; alkyl naphthalene sulfonate, ammonium diamylnaphthalene sulfonate, and sodium dinonyl naphthalene sulfonate.

Other anionic detergents are the olefin sulfonates including long chainalkene sulfonates, long chain hydroxyalkane sulfonates or mixtures ofalkenesulfonates and hydroxyalkanesulfonates. These olefin sulfonatedetergents may be prepared, in known manner, by the reaction of SO₃ withlong chain olefins (of 8-25 preferably 12-21 carbon atoms) of theformula RCH--CHR₁, where R is alkyl and R₁ is alkyl or hydrogen, toproduce a mixture of sultones and alkenesulfonic acids, which mixture isthen treated to convert the sultones to sulfonates. Examples of othersulfate or sulfonate detergents are paraffin sulfonates, such as thereaction products of alpha olefins and bisulfites (e.g. sodiumbisulfite), e.g., primary paraffin sulfonates of about 10-20 preferablyabout 15-20 carbon atoms; sulfates of higher alcohols; salts ofα-sulfofatty esters (e.g. of about 10 to 20 carbon atoms, such as methylα-sulfomyristate or α-sulfotallowate).

Examples of sulfates of higher alcohols are sodium lauryl sulfate,sodium tallow alcohol sulfate; Turkey Red Oil or other sulfated oils, orsulfates of mono- or diglycerides of fatty acids (e.g. stearicmonoglyceride monosulfate), alkyl poly(ethenoxy) ether sulfates such asthe sulfates of the condensation products of ethylene oxide and laurylalcohol (usually having 1 to 5 ethenoxy groups per molecule); lauryl orother higher alkyl glyceryl ether sulfonates; aromatic poly(ethenoxy)ether sulfates such as the sulfates of the condensation products ofethylene oxide and nonyl phenol (usually having 1 to 20 oxyethylenegroups per molecule, preferably 2-12).

The suitable anionic detergents include also the acyl sarcosinates (e.g.sodium lauroylsarcosinate) the acyl ester (e.g. oleic acid ester) ofisethionates, and the acyl N-methyl taurides (e.g. potassium N-methyllauroyl or oleyl tauride).

Other highly preferred water soluble anionic detergent compounds are theammonium and substituted ammonium (such as mono-, di- andtriethanolamine), alkali metal (such as sodium and potassium) andalkaline earth metal (such as calcium and magnesium) salts of the higheralkyl sulfates, and the higher fatty acid monoglyceride sulfates. Theparticular salt will be suitably selected depending upon the particularformulation and the proportions therein.

Nonionic surface active agents include those surface active or detergentcompounds which contain an organic hydrophobic group and a hydrophilicgroup which is a reaction product of a solubilizing group such ascarboxylate, hydroxyl, amido or amino with ethylene oxide or with thepolyhydration product thereof, polyethylene glycol.

As examples of nonionic surface active agents which may be used theremay be noted the condensation products of alkyl phenols with ethyleneoxide, e.g., the reaction product of octyl phenol with about 6 to 30ethylene oxide units; condensation products of alkyl thiophenols with 10to 15 ethylene oxide units; condensation products of higher fattyalcohols such as tridecyl alcohol with ethylene oxide; ethylene oxideaddends of monoesters of hexahydric alcohols and inner ethers thereofsuch as sorbitol monolaurate, sorbitol mono-oleate and mannitolmonopalmitate, and the condensation products of polypropylene glycolwith ethylene oxide.

Cationic surface active agents may also be employed. Such agents arethose surface active detergent compounds which contain an organichydrophobic group and a cationic solubilizing group. Typical cationicsolubilizing groups are amine and quaternary groups.

As examples of suitable synthetic cationic detergents there may be notedthe diamines such as those of the type RNHC₂ H₄ NH₂ wherein R is analkyl group of about 12 to 22 carbon atoms, such as N-2-aminoethylstearyl amine and N-2-aminoethyl myristyl amine; amide-linked aminessuch as those of the type R₁ CONHC₂ H₄ NH₂ wherein R is an alkyl groupof about 9 to 20 carbon atoms, such as N-2-amino ethyl stearyl amide andN-amino ethyl myristyl amide; quaternary ammonium compounds whereintypically one of the groups linked to the nitrogen atom are alkyl groupswhich contain 1 to 3 carbon atoms, including such 1 to 3 carbon alkylgroups bearing inert substituents, such as phenyl groups, and there ispresent an anion such as halide, acetate, methosulfate, etc. Typicalquaternary ammonium detergents are ethyl-dimethyl-stearyl ammoniumchloride, benzyl-dimethyl-stearyl ammonium chloride,benzyl-diethyl-stearyl ammonium chloride, trimethyl stearyl ammoniumchloride, trimethyl-cetyl ammonium bromide, dimethylethyl dilaurylammonium chloride, dimethyl-propyl-myristyl ammonium chloride, and thecorresponding methosulfates and acetates.

Examples of suitable amphoteric detergents are those containing both ananionic and a cationic group and a hydrophobic organic group, which isadvantageously a higher aliphatic radical, e.g., of 10-20 carbon atoms.Among these are the N-long chain alkyl aminocarboxylic acids e.g. of theformula ##STR3## the N-long chain alkyl iminodicarboxylic acids (e.g. ofthe formula RN(R'COOH)₂) and the N-long chain alkyl betaines e.g. of theformula ##STR4## where R is a long chain alkyl group, e.g. of about10-20 carbons, R' is a divalent radical joining the amino and carboxylportions of an amino acid (e.g. an alkylene radical of 1-4 carbonatoms), H is hydrogen or a salt-forming metal, R₂ is a hydrogen oranother monovalent substituent (e.g. methyl or other lower alkyl), andR₃ and R₄ are monovalent substituents joined to the nitrogen bycarbon-to-nitrogen bonds (e.g. methyl or other lower alkylsubstituents). Examples of specific amphoteric detergents areN-alkyl-beta-aminopropionic acid; N-alkyl-beta-iminodipropionic acid,and N-alkyl, N,N-dimethyl glycine; the alkyl group may be, for example,that derived from coco fatty alcohol, lauryl alcohol, myristyl alcohol(or a lauryl-myristyl mixture), hydrogenated tallow alcohol, cetyl,stearyl, or blends of such alcohols. The substituted aminopropionic andiminodipropionic acids are often supplied in the sodium or other saltforms, which may likewise be used in the practice of this invention.Examples of other amphoteric detergents are the fatty imidazolidinessuch as those made by reacting a long chain fatty acid (e.g. of 10 to 20carbon atoms) with diethylene triamine and monohalocarboxylic acidshaving 2 to 6 carbon atoms, e.g.1-coco-5-hydroxyethyl-5-carboxymethylimidazoline; betaines containing asulfonic group instead of the carboxylic group; betaines in which thelong chain substituent is joined to the carboxylic group without anintervening nitrogen atom, e.g. inner salts of 2-trimethylamino fattyacids such as 2-trimethylaminolauric acid, and compounds of any of thepreviously mentioned types but in which the nitrogen atom is replaced byphosphorus.

The instant compositions optionally contain a detergency builder of thetype commonly added to detergent formulations. Useful builders hereininclude any of the conventional inorganic and organic water-solublebuilder salts. Inorganic detergency builders useful herein include, forexample, water-soluble salts of phosphates, pyrophosphates,orthophosphates, polyphosphates, silicates, carbonates, zeolites,including natural and synthetic and the like. Organic builders includevarious water-soluble phosphonates, polyphosphonates,polyhydroxysulfonates, polyacetates, carboxylates, polycarboxylates,succinates, and the like.

Specific examples of inorganic phosphate builders include sodium andpotassium tripolyphosphates, phosphates, and hexametaphosphates. Theorganic polyphosphonates specifically include, for example, the sodiumand potassium salts of ethane 1-hydroxy-1,1-diphosphonic acid and thesodium and potassium salts of ethane-1,1,2-triphosphonic acid. Examplesof these and other phosphorus builder compounds are disclosed in U.S.Pat. Nos. 3,159,581, 3,213,030, 3,422,021, 3,422,137, 3,400,176 and3,400,148, incorporated herein by reference. Sodium tripolyphosphate isan especially preferred, water-soluble inorganic builder herein.

Non-phosphorus containing sequestrants can also be selected for useherein as detergency builders.

Specific examples of non-phosphorus, inorganic builder ingredientsinclude water-soluble inorganic carbonate, bicarbonate, and silicatesalts. The alkali metal, e.g. sodium and potassium, carbonates,bicarbonates, and silicates are particularly useful herein.

Water-soluble, organic builders are also useful herein. For example, thealkali metal, ammonium and substituted ammonium polyacetates,carboxylates, polycarboxylates and polyhydroxysulfonates are usefulbuilders in the present compositions and processes. Specific examples ofthe polyacetate and polycarboxylate builder salts include sodium,potassium, lithium, ammonium and substituted ammonium salts ofethylenediaminetetraacetic acid, nitrilotriacetic acid, oxydisuccinicacid, mellitic acid, benzene polycarboxylic (i.e., penta- and tetra-)acids, carboxymethoxysuccinic acid and citric acid.

Highly preferred non-phosphorus builder materials (both organic andinorganic) herein include sodium carbonate, sodium bicarbonate, sodiumsilicate, sodium citrate, sodium oxydisuccinate, sodium mellitate,sodium nitrilotriacetate, and sodium ethylenediaminetetraacetate, andmixtures thereof.

Other preferred organic builders herein are the polycarboxylate buildersset forth in U.S. Pat. No. 3,308,067, incorporated herein by reference.Examples of such materials include the water-soluble salts of homo- andcopolymers of aliphatic carboxylic acids such as maleic acid, itaconicacid, mesaconic acid, fumaric acid, aconitic acid, citraconic acid andmethylenemalonic acid.

The builders aforesaid, particularly the inorganic types, can functionas buffers to provide the requisite alkalinity for the bleachingsolution. Where the builder does not exhibit such buffer activity, analkaline reacting salt can be incorporated in the formulation.

The dry blend compositions of the invention contain about 0.1 to 50%(wt.), preferably 0.5 to 20% (wt.) of the herein carboxylic-sulfonicanhydride activator. It will be appreciated that the concentration ofactivator will depend on the concentration of the peroxygen bleachcompound which is governed by the particular degree of bleachingdesired. Higher or lower levels within the range will be selected tomeet the requirement of the formulator. As to the peroxygen bleachingagent, this is present to the extent of about 1 to 75% (wt.) of thecomposition, depending on the degree of bleaching activity desired.Generally speaking, optimal bleaching is obtained when the compositionsare formulated with peroxygen/aromatic carboxylicanhydride mole ratio inthe range of from about 20:1 to 1:3, preferably about 10:1 to about 1:1.The composition will contain a buffering agent in sufficient quantity tomaintain a pH of about 6 to 12 when the composition is dissolved inwater. The buffering agent can constitute from about 1% to about 95%(wt.) of the dry blended composition.

The herein activated bleach compositions can be provided for use incombination with a detergent agent or as a fully-formulated builtdetergent. Such compositions will comprise from about 5 to 50% of theactivated bleach system, from about 5 to 50% (wt.) of the detergentagent and optionally from about 1 to 60% (wt.) of a detergency builderwhich can also function as a buffer to provide the requisite pH rangewhen the composition is added to water.

The compositions herein can include detergent adjunct materials andcarriers commonly found in laundering and cleaning compositions. Forexample, various perfumes, optical brighteners, fillers, anti-cakingagents, fabric softeners, and the like can be present to provide theusual benefits occasioned by the use of such materials in detergentcompositions. Enzymes, especially the thermally stable proteolytic andlipolytic enzymes used in laundry detergents, also can be dry-mixed inthe compositions herein.

The solid peroxygen bleaching compositions herein are prepared by simplyadmixing the ingredients. When preparing mixed detergent/bleaches, theperoxygen and activator can be mixed either directly with the detergentcompound, builder, etc., or the peroxygen and activator can beseparately or collectively coated with a water-soluble coating materialto prevent premature activation of the bleaching agent. The coatingprocess is conducted according to known procedures in the art utilizingknown coating materials. Suitable coating materials include compoundssuch as magnesium sulfate hydrate, polyvinyl alcohol, or the like.

The following examples are illustrative of the compounds of theinvention:

EXAMPLE 1 Acetyl-p-toluenesulfonate ##STR5##

To a 500 ml Morton flask, equipped with an overhead air-driven stirrer,was added 100 ml of acetonitrile (previously distilled from phosphoruspentoxide) and 27.9 g (0.1 mole) of silver p-toluenesulfonate. Freshlydistilled acetyl chloride 7.85 g (0.1 mole) in 10 ml of acetonitrile wasadded slowly to the stirred mixture which was maintained below 20° C byexternal cooling. After approximately 5 hours, the acetonitrile wasremoved at ca 20 mm Hg (30° C) on a rotary evaporator. The residue waswashed with 150 ml of anhydrous ether. The ether solution was filtered.The solid material was washed four additional times with 50 ml portionsof ether. The ether filtrates were combined and cooled to -78° C. Theproduct which crystallized at this temperature, was recovered byfiltration and dried giving 14.0 g (65% yield) of a white solid with mp56°-60° C.

EXAMPLE 2 Benzoyl-p-toluenesulfonate ##STR6##

Benzoyl-p-toluenesulfonate was prepared from 14.1 g (0.1 mole) ofbenzoyl chloride and 27.9 g (0.1 mole) of silver p-toluenesulfonate inaccordance with the procedure described in Example 1. The reactionproduced 24.2 g (88% yield) of product with mp 70°-72° C. The producthad a neutralization equivalent of 137 (138 theory). Its proton NMR andinfrared spectrum was consistent with the given structure.

Anal. Calc'd for C₁₄ H₁₂ O₄ S: C, 60.86; H, 4.38; S, 11.60.

Found: C, 60.94; H, 4.63; S, 11.90.

The product was found to contain less than 20 ppm of silver.

EXAMPLE 3 Terephthaloyl-bis(p-toluenesulfonate) ##STR7##

Following the procedure of the previous examples,terephthaloyl-bis(p-toluenesulfonate) was prepared by allowing 10.15 g(0.05 mole) of terephthaloyl chloride to react for 13 hours with 27.9 g(0.1 mole) of silver p-toluenesulfonate in 200 ml of acetonitrile. Theacetonitrile was removed in a rotary evaporator. The residue was stirredwith several portions of hot benzene. The hot benzene fractions werefiltered, combined and cooled. The crystalline product which wasdeposited was recovered by filtration giving 17.2 g (73% yield) ofterephthaloyl bis-(p-toluenesulfonate) with mp 170°-176° C (lit.174°-176° C). The infrared spectrum was in good agreement with thatreported in the literature.

EXAMPLE 4 Isophthaloyl-bis(p-toluenesulfonate) ##STR8##

Following the procedure of the previous examples,isophthaloyl-bis(p-toluenesulfonate) was prepared from isophthaloylchloride and silver p-toluenesulfonate. There was obtained 13.5 g (57%yield) of crude product with mp 156°-167° C. A portion of the productwas recrystallized with acetonitrile, giving isophthaloylbis-(p-toluenesulfonate) with mp 172°-178° C. The infrared spectrum wasconsistent with the proposed structure.

Anal. Calc'd for C₂₂ H₁₈ O₈ S₂ : C, 55.69; H, 3.82; S, 13.15.

Found: C, 55.30; H, 3.83; S, 12.13.

EXAMPLE 5 Isophthaloyl-bis(methanesulfonate) ##STR9##

Following the procedure of the previous examples, isophthaloylbis(methanesulfonate) was prepared from 10.15 g (0.05 mole) ofisophthaloyl chloride and 20.2 g (0.1 mole) of silver methanesulfonate.After 16 hours reaction, the silver chloride precipitate was removed byfiltration. The filtrate was evaporated to dryness, giving a solidresidue with mp 133°-134.5° C. This residue was dissolved in 500 ml ofboiling benzene, which was filered to remove a small amount of silversalt. The filrate, on cooling, gave 13.9 g (86% yield) of fine whiteneedles with mp 131.5°-135.0° C. The infrared spectrum of the productwas consistent with the proposed structure.

Evaluation of Compounds as Bleach Activators

Compounds of the invention were evaluated for bleach activating efficacyby determining the increase in percent tea stain removal (%TSR) achievedby use of both the peroxygen source and activator compared with thatobtained by use of the peroxygen source alone. Both tests were performedunder otherwise identical low temperature laundering conditions. Theincrease in %TSR is called Δ%TSR. The evaluation was carried out in thepresence of a detergent formulation and sodium perborate tetrahydrate asthe source of peroxygen compound.

Tea-stained cotton and 65% dacron/35% cotton swatches (5×5) used inthese tests were prepared as follows: For each 50 swatches, 2000 ml oftap water was heated to boiling in a 4-liter beaker. Reflectancereadings were made on each swatch, using a Hunter Model D-40Reflectometer before staining. Two family size tea bags were added toeach beaker and boiling was continued for 5 minutes. The tea bags werethen removed and 50 fabric swatches were added to each beaker. Thedacron/cotton and 100% cotton swatches were boiled in the tea solutionfor 7 and 5 minutes respectively, after which the entire content of eachbeaker was transferred to a centrifuge and rotated for about 0.5minutes.

The swatches were then dried for 30 minutes in a standard householdlaundry drier. One hundred dry swatches were rinsed four times byagitating manually in 2000 ml portions of cold tap water. The swatcheswere dried in the household drier for approximately 40 minutes; theywere allowed to age for at least 3 days before use. Reflectance readingsfor each swatch were taken prior to bleaching tests, using a HunterModel D-40 Reflectometer.

Three stained cotton and polyester/cotton swatches were added to each ofseveral stainless steel Terg-O-Tometer vessels containing 1000 ml of0.15% detergent solution, maintained at a constant temperature of 105°F. The Terg-O-Tometer is a test washing device manufactured by the U.S.Testing Company. The detergent solution was prepared from a detergentformulation having the following composition (by weight):

25.0% -- Sodium tripolyphosphate

7.5% -- Sodium dodecylbenzenesulfonate (anionic surfactant)

4.0% -- Alcohol ether sulfate (obtained from 1 mole of C₁₆ -C₁₈ alcoholwith l mole ethylene oxide (anionic surfactant)

6.5% -- Alcohol (C₁₆ -C₁₈) sulfate (anionic surfactant)

1.3% -- Polyethylene glycol of about 6000 molecular wt.

35.4% -- Sodium sulfate

11.0% -- Sodium silicate

8.0% -- Moisture

0.8% -- Optical brightener

0.5% -- Carboxymethylcellulose

Measured quantities of sodium perborate tetrahydrate were added to eachvessel to provide the desired quantity of active oxygen (A.O.) followedby an amount of activator compound to give the bleaching A.O. levels. Ineach test run, the activator was excluded from at least oneTerg-O-Tometer vessel. The pH of each solution was adjusted to about10.0 with 5% sodium hydroxide solution. The Terg-O-Tometer was operatedat 100 cycles per minute for 15 or 30 minutes at the desiredtemperature. The swatches were then removed, rinsed under cold tap waterand dried in a household clothing drier. Reflectance readings were takenon each swatch and percent tea stain removal (%TSR) was calculated asfollows: ##EQU1## The increase of %TSR, termed Δ%TSR, was calculated bysubtracting the average %TSR in runs where the perborate was presentalone, from the average %TSR obtained in runs where both the activatorand the perborate were present. The test results are given in Table I.As the Δ%TSR values clearly demonstrate, the activator compounds of theinvention markedly improve the percentage of stain removal compared tothe peroxygen bleach compound alone.

Persuant to the requirements of the patent statutes, the principle ofthis invention has been explained and exemplified in a manner so that itcan be readily practiced by those skilled in the art, suchexemplification including what is considered to represent the bestembodiment of the invention. However, it should be clearly understoodthat, within the scope of the appended claims, the invention may bepracticed by those skilled in the art, and having the benefit of thisdisclosure, otherwise than as specifically described and exemplifiedherein.

                                      TABLE I                                     __________________________________________________________________________    Bleach Test.sup.(1) Results With Mixed Carboxylic Sulfonic Anhydrides                               Sodium  Mole                                                                  Perborate                                                                             Ratio                                                                 Tetrahydrate                                                                          of                                                                    to Give Perborate /                                                                           % TSR       Δ% TSR                Example                                                                            Structure        A.O. ppm                                                                              Activator                                                                             Cotton                                                                              Blend Cotton                                                                              Blend                 __________________________________________________________________________          ##STR10##       60      1       52    26    24    17                    2                                                                                   ##STR11##       60      1       55    34    19    33                    2                                                                                   ##STR12##       60      2       45    20     9     9                    2                                                                                   ##STR13##       60      1       53    31    19    21                    3                                                                                   ##STR14##       60      2       45    18    10     8                    3                                                                                   ##STR15##       30      2       33     6    -2    -4                    4                                                                                   ##STR16##       60      1       37    16     5     6                    5                                                                                   ##STR17##       60      1       52    18    21     8                      6.sup.(2)                                                                         ##STR18##       60      1       66    26    32    16                    __________________________________________________________________________     .sup.(1) All tests were performed at 105° F for 30 minutes.            .sup.(2) Purchased from Aldrich Chemical Company.                        

What is claimed is
 1. A process of removing soil and/or stains fromfabrics by immersing the fabrics in a peroxygen bleach bath containingas a peroxygen activator, an anhydride of a carboxylic acid with asulfonic acid selected from the formulae consisting of

    R.sub.1 --(SO.sub.2 OC(O)--R.sub.2).sub.n and (R.sub.1 --SO.sub.2 OC(O)).sub.n --R.sub.2

wherein n is an integer of 1 to 3; each of R₁ and R₂, which may be alikeor different, is selected from the class consisting of a 1 to 3 valenthydrocarbon radical derived from an alkane of 1 to 16 carbon atoms, acycloalkane of 3 to 7 carbon atoms and an arene of 6 to 12 aromaticcarbon atoms while taken together R₁ and R₂ can complete an o-phenyleneor an o-naphthalene ring, said hydrocarbon radicals optionally bearing 1to 3 substituents selected from the class consisting of alkoxy of 1 to16 carbon atoms on the arene, aliphatic carboxamido of 1 to 16 carbonatoms on the arene, alkyl of 1 to 16 carbon atoms on the arene,benzamido on the arene, nitro, chlorine, bromine and fluorine.
 2. Theprocess according to claim 1 wherein the mole ratio of peroxygen toactivator is from about 20:1 to about 1:3.
 3. The process according toclaim 2 wherein the peroxygen is sodium perborate tetrahydrate.
 4. Theprocess according to claim 2 wherein the quantity of peroxygen issufficient to provide from about 2 ppm to about 2000 ppm of activeoxygen.
 5. The process according to claim 1 wherein the bleach solutioncontains a detergent agent.
 6. The process according to claim 1 whereinthe pH of the bleach solution is maintained by means of a bufferingagent.
 7. The process according to claim 1 wherein the activator isselected from the class consisting of acetyl-p-toluenesulfonate,benzoyl-p-toluenesulfonate, terephthaloyl-bis(p-toluenesulfonate),isophthaloyl-bis(p-toluenesulfonate),isophthaloyl-bis(methanesulfonate), and o-sulfobenzoic anhydride.